In 1905, Paulémile exhibited at the Salon des Independants for the first time, showing an impressionist landscape entitled Bords de l'Epte á Eragny, and although his father had supported his desire to be an artist, his mother was eager for him to learn a more practical trade. In 1908, he put aside his artistic pursuits and worked as an automobile mechanic and test-driver, and then as a lace and textile designer, thus allowing him a little time to paint. While Paulémile was still working at the lace factory his brother Lucien, who lived in London, asked him to send over some watercolors, and the sale of these encouraged Paulémile to leave the factory and dedicate himself to painting.
In 1967, he had his first one-man show in the United States at Wally Findlay Galleries in NY. This led to widespread recognition and a degree of professional success that few Pissarro artists had known during their lifetime. Since his death in 1972, Paulémile's paintings have been exhibited around the world.